Trim away any vegetation from the metal fence that could interfere with your ability to paint.
Wash the fence using a pressure washer. Allow the metal fence to dry.
Abrade the metal fence to promote paint adhesion by applying a coat of galvanized metal etching primer. Use a mini roller to apply the primer. Eliminate runs and drips by brushing them smooth using a 2- to 3-inch latex paintbrush manufactured for latex paints. Allow the etching primer to dry and cure for four hours.
Wash all painting instruments with water.
Apply a coat of exterior acrylic latex paint using the mini roller stocked with a fresh, clean roller cover. Apply in the same way you applied the primer. Allow the paint to dry for two hours, and then apply another coat if you can see the primer showing through.